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Sintesis Hidrogel Kopolimer Pati Iles-iles Dengan Asam Akrilat, Akrilamida Dan Metilenabisakrilamida Sebagai Pembenah Tanah

机译:以丙烯酸,丙烯酰胺和甲基烯丙基双丙烯酰胺为土壤改性剂的Iles-iles淀粉共聚物水凝胶的合成

摘要

SINTHESYS OF HYDROGEL COPOLYMER OF KONJAC STARCHWITHACRYLICACID, ACRYLAMIDE AND METHYLENEBISACRYLAMIDE FOR SOILAMENDMENT. Graft copolymer hydrogel of konjac starch, acrylic acid, acrylamide and N,N-methylenebisacrylamide was synthesized by techniques of polimerisation in solution with water as solvent and initiator of potassium persulfate. Konjac starches were obtained by homogenizing Konjac tuber with water and washed it with methanol several times. Konjac starch obtained with this method can produce a clear solution with up to 5 %w/w solubility. Polymerization in solution was done without nitrogen gas bubbling. The resulting hydrogel determined its water absorption and it chemical structure based on the FT-IR spectra. Based on the weight of the resulting hydrogel, the synthesis proceeds in 100 % polymerization at a temperature of 55 oC. The resulting hydrogel at certain polymerization conditions has water absorption of up to 51 times of its weight. The polymerization condition was achieved at Konjac starch concentration ratio to acrylic acid, acrylamide and N,N-methyl enebisacrylamide = 1: 3: 3: 0.01. Graft copolymer hydrogel was then used as an amendment for sandy soil to control the soil ability to store and evaporate thewater. Sandy soil mixed with 0.5 %w/whydrogel can absorb water up to two and a half times than in the absence of hydrogel and hold more than half of the water that is absorbed during the equilibrium evaporation and absorption ofwater. Equilibrium evaporation and water absorption was reached after 5 days at temperatures of 23-29 oC and humidity of 40-83 %.
机译:康佳淀粉丙烯酸,丙烯酰胺和亚甲基二丙烯酰胺的水合共聚物的土壤改性。以水为溶剂,过硫酸钾引发剂为溶液,通过溶液聚合反应,合成了魔芋淀粉,丙烯酸,丙烯酰胺和N,N-亚甲基双丙烯酰胺接枝共聚物水凝胶。通过用水将魔芋块茎匀浆并用甲醇洗涤几次来获得魔芋淀粉。用这种方法获得的魔芋淀粉可以产生澄清的溶液,其溶解度高达5%。在溶液中进行聚合而没有氮气鼓泡。所得水凝胶根据FT-IR光谱确定其吸水率和化学结构。基于所得水凝胶的重量,合成在55 oC下以100%聚合进行。在某些聚合条件下,所得水凝胶的吸水率高达其重量的51倍。在魔芋淀粉与丙烯酸,丙烯酰胺和N,N-甲基亚乙基双丙烯酰胺的浓度比为1:3:3:0.01的条件下达到聚合条件。然后将接枝共聚物水凝胶用作沙质土壤的改良剂,以控制土壤储存和蒸发水的能力。混合有0.5%w / w水凝胶的沙质土壤吸收水分的量是不存在水凝胶的情况下的两倍半,并且在平衡蒸发和吸收水的过程中可以吸收一半以上的水分。 5天后在23-29 oC的温度和40-83%的湿度下达到平衡蒸发和吸水率。

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